首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6384篇
  免费   594篇
  国内免费   383篇
化学   1901篇
晶体学   78篇
力学   1153篇
综合类   52篇
数学   1018篇
物理学   3159篇
  2023年   47篇
  2022年   85篇
  2021年   147篇
  2020年   173篇
  2019年   139篇
  2018年   157篇
  2017年   167篇
  2016年   129篇
  2015年   148篇
  2014年   200篇
  2013年   541篇
  2012年   316篇
  2011年   413篇
  2010年   304篇
  2009年   362篇
  2008年   358篇
  2007年   381篇
  2006年   374篇
  2005年   323篇
  2004年   322篇
  2003年   297篇
  2002年   265篇
  2001年   187篇
  2000年   198篇
  1999年   128篇
  1998年   181篇
  1997年   151篇
  1996年   112篇
  1995年   102篇
  1994年   91篇
  1993年   77篇
  1992年   85篇
  1991年   41篇
  1990年   53篇
  1989年   32篇
  1988年   38篇
  1987年   23篇
  1986年   29篇
  1985年   36篇
  1984年   24篇
  1983年   9篇
  1982年   27篇
  1981年   16篇
  1980年   12篇
  1979年   11篇
  1978年   13篇
  1977年   5篇
  1976年   9篇
  1973年   9篇
  1957年   4篇
排序方式: 共有7361条查询结果,搜索用时 31 毫秒
1.
2.
In this paper, we study the following Klein–Gordon–Maxwell system Δu+(λa(x)+1)u(2ω+ϕ)ϕu=f(x,u),inR3,Δϕ=(ω+ϕ)u2,inR3.Using variational methods, we obtain the existence of ground state solutions under some appropriate assumptions on a and f.  相似文献   
3.
This review gives an overview of the evolution of the technology of condensed mode cooling, primarily for the case of ethylene polymerization on supported catalysts in fluidized bed reactors. It is well known that this mode of heat removal is quite effective in allowing polyolefin manufacturers to increase significantly production rates. What is perhaps less well understood are all of the issues that, in addition to the effect of the latent heat of vaporization of injected liquid components, also have an impact on the rate of production and behavior of the reactor. However, the liquid components injected into the reactor can vaporize rapidly under full‐scale conditions, leaving behind several heavy components (with respect to ethylene) that have numerous effects on how the particles behave, on the reaction rate, and on fluidization, fouling, and other parameters related to reactor and process performance.  相似文献   
4.
We study ground states of two-component Bose–Einstein condensates (BEC) with trapping potentials in R2, where the intraspecies interaction (?a1,?a2) and the interspecies interaction ?β are both attractive, i.e, a1, a2 and β are all positive. The existence and non-existence of ground states are classified completely by investigating equivalently the associated L2-critical constraint variational problem. The uniqueness and symmetry-breaking of ground states are also analyzed under different types of trapping potentials as ββ?=a?+(a??a1)(a??a2), where 0<ai<a?:=6w622 (i=1,2) is fixed and w is the unique positive solution of Δw?w+w3=0 in R2. The semi-trivial limit behavior of ground states is tackled in the companion paper [12].  相似文献   
5.
A difunctional benzoxazine (coPh‐apa) with a conjugated alkyne group is synthesized by the oxidative coupling reaction from a monocycle‐benzoxazine (Ph‐apa) containing an alkyne group. A model compound, 1,4‐diphenylbutadiyne (coPa), is used to study the curing reaction process of coPh‐apa by DSC, Fourier transform infrared spectroscopy, and 13C NMR, and the results suggest that the conjugated alkyne groups are involved in the crosslinking reaction via the trimerization reaction of the conjugated alkynyl groups and the Diels–Alder reaction. Furthermore, thermal properties of the polybenzoxazine are studied by dynamic thermomechanical analysis and thermogravimetric analysis. A glass‐transition temperature (Tgs) of as high as 412 °C and a char yield of 75.6% at 800 °C under nitrogen are obtained with the aid of the conjugated alkyne groups. Its excellent heat resistance dominates most thermosetting resins and will serve for heat shields. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1587–1592  相似文献   
6.
大尺寸低缺陷碳化硅(SiC)单晶体是功率器件和射频(RF)器件的重要基础材料,物理气相传输(physical vapor transport, PVT)法是目前生长大尺寸SiC单晶体的主要方法。获得大尺寸高品质晶体的核心是通过调节组分、温度、压力实现气相组分在晶体生长界面均匀定向结晶,同时尽可能减小晶体的热应力。本文对电阻加热式8英寸(1英寸=2.54 cm)碳化硅大尺寸晶体生长系统展开热场设计研究。首先建立描述碳化硅原料受热分解热质输运及其多孔结构演变、系统热输运的物理和数学模型,进而使用数值模拟方法研究加热器位置、加热器功率和辐射孔径对温度分布的影响及其规律,并优化热场结构。数值模拟结果显示,通过优化散热孔形状、保温棉的结构等设计参数,电阻加热式大尺寸晶体生长系统在晶锭厚度变化、多孔介质原料消耗的情况下均能达到较低的晶体横向温度梯度和较高的纵向温度梯度。  相似文献   
7.
8.
This article deals with the various heat source responses in a transversely isotropic hollow cylinder under the purview of three-phase-lag (TPL) generalized thermoelasticity theory. In presence of magnetic field and due to the rotating behavior of the cylinder, the governing equations are redefined for generalized thermoelasticity with thermal time delay. In order to obtain the stress, displacement and temperature field, the field functions are expressed in terms of modified Bessel functions in Laplace transformed domain. When the outer radius of hollow cylinder tends to infinity, the corresponding results are discussed. Finally an appropriate Laplace transform inversion technique is adopted.  相似文献   
9.
The first example of application of nanosized polystyrene-based cation exchanger (NSCE) with sulfo groups as a dynamic coating of capillary walls was demonstrated. The conditions of dynamic coating formation were optimized and ensured the long-term stability of the coating. Capillary-to-capillary and day-to-day repeatabilities were 4% and 3%, correspondingly. The NSCE coating stability at various pH and influence of pH on the EOF mobility were investigated. The developed NSCE-modified coated capillaries provided improved resolution (Rs = 0.9–3.2 for catecholamines and Rs = 1.7–2.8 for amino acids) and efficiencies (330–520 ×103 t.p./m) of basic analytes, which are 1.5 times higher compared to untreated capillary. The optimized conditions were as follows: 50 mM phosphate buffer solution at pH 2.2 with 5 μM NSCE. The effect of the NSCE concentration in BGE on the electrophoretic mobilities of the analytes was investigated. The various online concentration techniques were tested in order to decrease the LODs. The simultaneous application of NSCE capillaries and field-amplified sample stacking provided the lowest LODs of catecholamines and amino acids and allowed to determine these analytes in human urine.  相似文献   
10.
采用SST k-w低雷诺数湍流模型对加热条件下超临界压力CO2在内径di=22.14 mm,加热长度Lh=2440 mm水平圆管内三维稳态流动与传热特性进行了数值计算.通过超临界CO2在水平圆管内的流动传热实验数据验证了数值模型的可靠性和准确性.首先,研究了超临界压力CO2在水平圆管内的流动传热特点,基于超临界CO2在类临界温度Tpc处发生类液-类气“相变”的假设,揭示了水平圆管顶母线和底母线区域不同的流动传热行为.然后,分析了热流密度qw和质量流速G对水平圆管内超临界压力CO2流动换热的影响,通过获取流体域内的物性分布、速度分布和湍流分布等详细信息,重点解释了不同热流密度qw和质量流速G下顶母线内壁温度Tw,i分布产生差异的传热机理,分析结果确定了类气膜厚度d、类气膜性质、轴向速度u和湍动能k是影响顶母线壁温分布差异的主要因素.研究结果可以为超临界压力CO2换热装置的优化设计和安全运行提供理论指导.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号